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an error or a typo when doing the post? It could perhaps render your main.cf unparsable.
Other than that i think your config should work, when just skimming it. But opening up the whole subnet for relay seems a bit generous It might work with a single host entry ie,
For what it is worth - I ended up just reloading the BUBBA updating it and redoing my changes. The only additional changes I made were commenting out mynetworks_style = subnet and adding the mynetworks = 172.16.10.0/24 back in. Apparently I had somehow deleted something erroneously with VI - Imagine that.....
I have looked at the copy of the main.cf I had, and it did have the incorrect line, that was probably it all along....